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A QSAR using Comparative Molecular Field Analysis (CoMFA) is developed for a set of 23 catalysts containing bis-oxazoline or phosphino-oxazoline ligands that are known to induce asymmetry during the D...
Enantioselective complexation of chiral lariat crown ethers and chiral primary alkylammonium perchlorates
Chiral lariat crown ethers enantioselectivity complexation properties molecular recognition NMR titration
2011/4/6
In order to investigate the enantiomeric recognition abilities toward 2 chiral alkylammonium perchlorates (AmI, AmII) by 1H-NMR titration method in CDCl3, 4 chiral lariat ethers 8-11 with a (p-methoxy...
摘要 应用HPLC方法在100mm×4.6mm的Chiral-AGP手性固定相柱上,分离氟布洛芬、 西替利嗪、罗哌卡因等手性药物和反式-2-苯基环丙基硼酸的对映体混合物。考 察了流动相pH值和缓冲液浓度等对样品在柱上的保留和分离的影响,研究了流动相 中加入四种不带电荷的有机添加剂乙腈、甲醇、正丙醇和异丙醇以及加入不同浓度 的有机添加剂等对对映体分离性的影响。此方法用于手性药物合成中的对映过量值 的...
Enantioseparation of Novel Chiral Tetrahedral Clusters on a Chiral Stationary Phase (CSP) by High Performance Liquid Chromatography
high performance liquid chromatography chiral stationary phase chiral tetrahedral clusters enantioseparation
2007/12/13
Enantioseparation of Novel Chiral Tetrahedral Clusters on a Chiral Stationary Phase (CSP) by High Performance Liquid Chromatography。
Uniformly Sized Molecularly Imprinted Polymers: Their Applications to Chiral Separation and Bioanalysis
molecularly imprinted polymer (MIP) restricted access media-MIP (RAM-MIP) chiral separation bioanalysis
2007/12/13
Uniformly Sized Molecularly Imprinted Polymers: Their Applications to Chiral Separation and Bioanalysis。
Chiral Separations by Ligand-Exchange Micellar Electrokinetic
chiral separation micellar electrokinetic chromatography microemulsion electrokinetic chromatography ligand exchange
2007/12/13
Chiral Separations by Ligand-Exchange Micellar Electrokinetic。
专著信息
书名
Synthesis, spectroscopic characterisation and structure of the first chiral heteroleptic bis(phthalocyaninato) rare earth complexes. Chem.
语种
英文
撰写或编译
作者
Jianzhuang Jiang
第一作者单位
出版社
Commun., 2...
专著信息
书名
Asymmetric reactions catalyzed by chiral titanium complexes
语种
英文
撰写或编译
作者
Fuxue Chen,Xiaoming Feng,Yaozhong Jiang
第一作者单位
出版社
ARKIVOC, 2003, (II), 21-31
出版地
出版日期
2003年
月
日
标准书号
介质类型
页数
字数
开本
相...
专著信息
书名
Catalytic Enantioselective Synthesis of 2,6-Disubstituted Dihydropyrones by Hetero-Diels-Alder Reaction Using Chiral Binol_Ti(IV) complex
语种
英文
撰写或编译
作者
Huang Yaozong,Feng Xiaoming,Wang Bin et...
专著信息
书名
Asymmetric Cyanosilylation of Ketones Catalyzed by Chiral N-oxide-Titanium Complex
语种
英文
撰写或编译
作者
Shen Yongcun,Feng Xiaoming,Zhang Guolin
第一作者单位
出版社
Synlett, 2002, 1353-5
出版地
出版日期
2002年
月
日
标准...
含潜在异构手性双臂配体的螺旋组装和手性聚集(Helical Assembly and Chiral Aggregations Based on Atropisomeric Molecular Clips)
晶体结构 配合物 螺旋组装 手性聚集
2010/8/18
采用具有潜在异构手性的双臂配体,双吡啶二甲基联苯-2,2′-二酰肼,合成了4个双核螺旋配合物。配体与CdI2和Cu(NO3)2反应得到双核单螺旋化合物1和2,在化合物2中,由于C-H…π和π…π的协同相互作用沿ab面形成单一手性的二维平面。双核双螺旋化合物3(Ni(Ⅱ))和4(Co(Ⅱ))中的金属中心表现相同的绝对构型,说明含异构手性的配体能够把金属中心的手性从一个中心传递到另一个中心。
An Atropisomeric Chiral 2,2'-bipyridyl-3,3'-dicarboxylic Acid and Corresponding Platinum(II) Complex
Platinum complexes 3,3'-dicarboxyl-2,2'-bipyridine ligand Crystal structure Spontaneous resolution Hydrogen bonding
2010/4/20
2,2'-Bipyridyl-3,3'-dicarboxylic acid (H2BDC) spontaneously resolves on crystallization from water, giving monohydrated crystals of the space group P212121. In any individual crystal, all the atropiso...
A Computational Investigation for the Chiral Chromatographic Separation of Benzimidazole Type Sulphoxides
Molecular modelling sulphoxides molecular mechanics chiral separation chromatography
2010/4/21
The computational study of chromatographic separations has become increasingly important in recent years. It supplies useful information about the mechanism of chromatographic separations and the desi...
Auxiliary Controlled Intramolecular 1,3-Dipolar Cycloaddition Reactions of Chiral Azomethine Ylides
Auxiliary Controlled Intramolecular 1,3-Dipolar Cycloaddition Reactions Chiral Azomethine Ylides
2010/6/29
Intramolecular 1,3-dipolar cycloaddition reactions of chiral azomethine ylides obtained by thermal ring opening of chiral aziridines 7a, b and 8a, b are investigated. Synthesis of these aziridines 7a,...