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Abstract: The purpose of this study was to characterize more fully the surface charge characteristics of the end-member smectite in illite-smectite (I-S) mixed-layer phases found previously in pelitic...
Abstract: Adsorption studies of aromatic hydrocarbons of various molecular sizes on organo-clays in aqueous solution were carried out for characterizing the surface heterogeneity of organo-clays. Benz...
Several soil and reference smectites and vermiculites and one reference illite were examined by high-resolution transmission electron microscopy (HRTEM) to decipher the nanostructure and layer charge ...
Water vapor adsorption isotherms were measured for samples of loessial soil clays modified by removing organic matter and Fe and Al compounds. The isotherms were analyzed by the exponential adsorption...
Abstract: The heterogeneity of sites for Ca→K exchange was examined by microcalorimetry in the <0.2-&micro;m fractions of some selected smectites. Six groups of sites, ranging in exothermic exchange e...
Measurements of the differential heats of K-Ca exchange are used to show that 6 groups of sites (ranging from −13.8 to −5.1 kJ/eq and with as many as 4 in any one sample) exist in kaolins ...
The broad charge heterogeneity typical of nearly all smectites is not necessarily characteristic of vermiculites. In addition to vermiculites with pronounced heterogeneity, minerals with no or only li...
Integrated intensities of the fundamental modes of vibrations of ammonium in heat-treated, NH4+-exchanged swelling minerals permits (1) a quantitative determination of the amount of tetrahedral substi...
Abstract: A comparison is made of the ion exchange behavior, towards the cobalt ion, of five sodium montmorillonite clays. The selectivity for the bivalent ion at low cobalt loading is correlated with...
A specimen montmorillonite (Arizona bentonite) was treated with hydroxy-aluminum solutions of various basicity. The cation exchange sites of this clay were found not to be homogeneous in their strengt...

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