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Pyrope-grossular solid solutions, (Mg,Ca) Al Si O , of composition Py Gr and Py Gr were3 2 3 12 85 15 75 25 synthesized at 1000, 1200, and 1400 ?C and 30 kbars in a piston-cylinder device. The synt...
Within the framework of the Adam-Gibbs (configurational entropy) theory of viscosity,it is shown that for a given composition, the ratio of parameters Be (a temperature inde-pendent constant) to Sc( ...
Anewhigh-pressureMgTiO phasewiththelithiumniobatestructure(R3c)hasbeen roveredfromexperimentsat21GPaand1200C.Phaseswiththelithiumniobate structurewerealsosynthesizedforintermediatecompositionsbetwee...
Exsolvedpairsofhornblende and cummingtonite from two localities in southern New England, U.S.A.,have been studied using transmission electron microscopy(TEM) to measurethe crystallographic orientation...
Curietemperatures (Td ofthe (Fe304)x(MgA1204)1-xsolid solution have been deter-minedfrom measurementsofmagneticsusceptibility (x)vs.temperature. Thetrend in Te vs.composition extrapolates to 0Katx =0...
The enthalpy ofordering ofAland Sibetween tetrahedral sites in framework structures is now known from several studies to bein the range 0.3-1.4 eVper two Al-O-Si linkages, depending on the structure a...
Raman spectra ofNa2Si20sglassand Na2Si20sliquid have been collected in situ to pressuresof16GPaat300Kand 10GPaat885K.Inglasscompressed at300K,bands associated withintertetrahedral bridging 0 atoms de...
Smectite single crystals of superior quality were synthesized at high pressures and temperatures using a modified belt type high pressure apparatus. Pressure-temperature conditions were established fo...
Abstract: Ammonium-saponite is hydrothermally grown at temperatures below 300°C from a gel with an overall composition corresponding to (NH4)0.6Mg3Si3.4Al0.6O10(OH)2. The synthetic saponite and co-exi...
Comparing the state of reaction advancement of I/S (illite content of illite/smectite mixed layer minerals) and organic matter (vitrinite reflectance) in instances of high temperature gradients allows...
Mixtures of magnetite and goethite were formed by the slow oxidation of mixed FeCl2-AlCl3 solutions in an alkaline environment at room temperature. The compositions of the products ranged from almost ...
A high-pressure, high-temperature cell was used to monitor the basal X-ray powder diffraction spacing of Na-saturated Cheto montmorillonite in contact with NaCl solutions at temperatures as high as 20...
The dehydration temperature of K-montmorillonite, obtained by ion exchange of a Na-montmorillonite, was determined at pressures to 2 kbar, using high-pressure differential thermal analysis. Dehydratio...
Glauconite has been synthesized at low temperature by precipitation of Fe-hydroxides from Si-, Fe-, Al-, and K-containing solutions under reducing conditions. The compositions favorable for the synthe...
Abstract: Dimensional changes in kaolinite pellets as a function of temperature show two sharp shrinkage “steps,” at about 450–550°C and 900–980°C, which are roughly comparable in magnitude. Isotherma...

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