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Four-Stroke Engine Cycle Produces Hydrogen from Methane and Captures CO2
Four-Stroke Engine Cycle Produces Hydrogen Methane CO2
2017/3/14
When is an internal combustion engine not an internal combustion engine? When it’s been transformed into a modular reforming reactor that could make hydrogen available to power fuel cells wherever the...
The 2nd International Conference on Hydrogen Atom Transfer (iCHAT 2017) will be held from July 2-6 2017 in Monteporzio Catone, a small village in the “Castelli romani” area about 20 km south of Rome. ...
New Findings Boost Promise of Molybdenum Sulfide for Hydrogen Catalysis
Boost Promise Molybdenum Sulfide Hydrogen Catalysis
2016/12/13
MoS2 presents a promising low-cost catalyst for the hydrogen evolution reaction (HER), but the understanding about its active sites has remained to be limited. Here we present an unambiguous study for...
Putative Hydrogen Bond to Tyrosine M208 in Photosynthetic Reaction Centers from Rhodobacter capsulatus Significantly Slows Primary Charge Separation
Coagulation Nano TiO2 Nano Al2O3 Breakage Fractal dimension
2016/5/25
Slow, ～50 ps, P* → P(+)HA(-) electron transfer is observed in Rhodobacter capsulatus reaction centers (RCs) bearing the native Tyr residue at M208 and the single amino acid change of isoleucine at M20...
Experimental quantification of electrostatics in X-H⋅⋅⋅π hydrogen bonds
Experimental quantification electrostatics X-H⋅ ⋅ ⋅ π hydrogen bonds
2016/5/25
Hydrogen bonds are ubiquitous in chemistry and biology. The physical forces that govern hydrogen-bonding interactions have been heavily debated, with much of the discussion focused on the relative con...
Direct Measurements of Electric Fields in Weak OH••π Hydrogen Bonds
Direct Measurements Electric Fields Weak OH• • π Hydrogen Bonds
2016/5/25
Hydrogen bonds and aromatic interactions are of widespread importance in chemistry, biology, and materials science. Electrostatics play a fundamental role in these interactions, but the magnitude of t...
Electrostatic Fields Near the Active Site of Human Aldose Reductase:2.New Inhibitors and Complications Caused by Hydrogen Bonds
Humans Nitriles Aldehyde Reductase Spectrophotometry, Infrared Spectroscopy, Fourier Transform Infrared Binding Sites Catalytic Domain Protein Binding Kinetics Hydrogen Bonding
2016/5/25
Vibrational Stark effect spectroscopy was used to measure electrostatic fields in the hydrophobic region of the active site of human aldose reductase (hALR2). A new nitrile-containing inhibitor was de...
Conjugation in hydrogen-bonded systems
molecular clusters electron density distribution hydrogen bonds conjugation cooperativity
2012/4/19
Analysis of the electron density distribution in clusters composed of hydrogen fluoride, water, and ammonia molecules, especially within the hydrogen-bond domains, reveals the existence of both \sigma...
Photochemical Hydrogen Abstraction and Electron Transfer Reactions of Tetrachlorobenzoquinone with Pyrimidine
Tetrachlorobenzoquinone Thymine Uracil Triplet state Hydrogen abstrac-tion Electron transfer Laser flash photolysis
2012/4/5
Pentachlorophenol, a widespread environmental pollutant that is possibly carcinogenic to humans, is metabolically oxidized to tetrachloroquinone (TCBQ) which can result in DNA damage. We have investig...
Heterogeneous Uptake of Hydrogen Peroxide on Mineral Oxides
Kinetics Hydrogen peroxide Heterogeneous uptake Atmospheric lifetime
2012/4/5
The interaction of mineral oxides (α-Al2O3, MgO, Fe2O3, and SiO2) with hydrogen peroxide was investigated using the Knudsen cell reactor. The initial reactive uptake coefficients for the commercially ...
Hydrogen Production From Crude Bio-oil and Biomass Char by Electrochemical Catalytic Reforming
Hydrogen Bio-oil Biomass char Ni-Al2O3 catalyst CuZn-Al2O3 catalyst Electro chemical catalytic reforming
2012/4/5
We reports an efficient approach for production of hydrogen from crude bio-oil and biomass char in the dual fixed-bed system by using the electrochemical catalytic reforming method. The maximal absolu...
An efficient one-pot synthesis of dihydropyrimidinones catalyzed by zirconium hydrogen phosphate under solvent-free conditions
Biginelli reaction solvent-free zirconium hydrogen phosphate
2010/10/18
A simple, efficient, and practical procedure for the Biginelli reaction using zirconium hydrogen phosphate [Zr(H2PO4)2] as a novel solid acid catalyst is described under solvent-free conditions in hig...
Nano-Molar Level Hydrogen Peroxide Detection by Horseradish Peroxidase Adsorbed Cup-Stacked Carbon Nanotube Electrodes and Applications to L-Glutamate Detection
Nano-Molar Level Hydrogen Peroxide Detection by Horseradish Peroxidase Adsorbed Cup-Stacked Carbon Nanotube Electrodes and Applications to L-Glutamate Detection
2010/9/13
We have developed a simple fabrication method of a highly sensitive direct electron transfer-type electrochemical biosensor for hydrogen peroxide by use of cup-stacked carbon nanotubes (CSCNTs). The C...
Prussian Blue Electrodeposited on Nano Ag-coated Multiwalled Carbon Nanotubes Composite for the Determination of Hydrogen Peroxide
Prussian Blue Electrodeposited Nano Ag-coated Multiwalled Carbon Nanotubes Composite Hydrogen Peroxide
2010/9/17
A prussian blue (PB) electrodeposited on nano Ag-coated multiwalled carbon nanotubes (nano Ag-MWNTs) was reported. Also a PB/nano Ag-MWNTs composite modified glass carbon (GC) electrode was used to in...
Micellar-mediated Extractive Spectrophotometric Determination of Hydrogen Sulfide/Sulfide through Prussian Blue Reaction: Application to Environmental Samples
Micellar-mediated Extractive Spectrophotometric Determination Hydrogen Sulfide Prussian Blue Reaction
2010/9/17
A sensitive surfactant-mediated extractive spectrophotometric method has been developed, based on the reaction of ferric iron with sulfide to form ferrous iron and its subsequent reaction with ferricy...