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Clustering, Reorientation Dynamics, and Proton Transfer In Glassy Oligomeric Solids
imidazole proton transfer reorientation
2014/11/20
We have modelled structures and dynamics of hydrogen bond networks that form from imidazoles tethered to oligomeric aliphatic backbones in crystalline and glassy phases. We have studied the behavior o...
Preparation of 1,5-Diketones by Addition of Cyclohexanone to Chalcones under Solvent-free Phase Transfer Catalyst Condition
Chalcones 1,5-Diketones Solvent-free Phase Transfer Catalyst Michael Addition
2010/4/16
Eight different chalcone-1,5-diketone derivatives (5a-h) were prepared by the reaction of chalcone derivatives (3a-h) with cyclohexanone under the solvent-free phase transfer catalyst condition with m...
Heterogeneous Electron Transfer Rate Constants of Viologen Monocations at a Platinum Disk Electrode
Viologen monocations experimental rate constant for heterogeneous electron transfer process theoretical rate constant for heterogeneous electron transfer process
2010/4/19
Experimental values of rate constants for the heterogeneous transfer of electrons to methyl viologen, diquat viologen, benzyl viologen and n-butyl viologen monocations were determined. The process was...
Heterogeneous Electron Transfer Rate Constants of Viologen at a Platinum Disk Electrode
Heterogeneous Electron Transfer Rate Constants of Viologen a Platinum Disk Electrode
2010/4/19
The transfer of electrons to the dications of viologens including methyl viologen, diquat, benzyl viologen and n-butyl viologen was studied at the surface of a platinum disk electrode. The rate consta...
Heme Transfer Reactions: An Important Prerequisite for Synthetic Oxygen Carriers
Heme Transfer Reactions Important Prerequisite Synthetic Oxygen Carriers
2010/7/1
Electronic changes of iron- and metal free porphyrins are reviewed in light of their importance to modify the ferri/ferro reduction potential and energy dissipation between ligated carbon monoxide and...