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酞菁键合硅胶的制备及分离取代酞菁异构体(Preparation of Phthalocyanine Bonded Silica Gel for the Separation of Phthalocyanine Isomers)
酞菁键合硅胶 制备 分离 异构体
2010/8/18
制备和表征了一种新的酞菁键合硅胶,三-β-(辛巯基)-β-(磺酰胺基)-酞菁铜键合硅胶。研究了该键合酞菁硅胶作为HPLC固定相的基本色谱性能。实验结果表明,该固定相可以分离四-α-(2,2,4-三甲基-3-戊氧基)酞菁(铜、镍)的4种异构体,也可以观察到四-α-(2,2,4-三甲基-3-戊氧基)无金属酞菁的4种异构体,而商业C18(VERTEX Eurospher)却只能观察到两组峰,表明这种酞菁...
Separation Process Of Citric Acid with Tertiary Amines/Diluents in Supercritical CO2
Citric Acid Reactive Extraction Supercritical CO2 Hostarex A 327 Oleyl Alcohol
2010/4/22
Reactive extraction of citric acid was investigated at atmospheric and supercritical conditions. The most suitable diluent and amine from among the tertiary amines and eight different diluents were de...